ADR hazard number X432

Hazard identification number X432 on the orange plate: pyrophoric solid that reacts dangerously with water, giving off flammable gas.

Printed in the upper half of the orange-coloured plate above the UN number, X432 identifies a pyrophoric solid that reacts dangerously with water, giving off flammable gas. The leading X warns that the substance reacts dangerously with water, so water may be applied only with expert approval.

Digit by digit
Xprefix X: the substance reacts dangerously with water; water may be used on it only with the approval of experts
4flammable solid, or a self-heating solid
3flammable liquid (vapours) or gas, or a self-heating liquid
2gas given off, either because of pressure or through a chemical reaction

Note. In the 5.3.2.3.2 list this entry carries footnote 1: water is not to be used except with the approval of experts. Number and meaning pairing checked against a second text extraction of the list.

Refers to: 5.3.2.3.1; 5.3.2.2.3; Table A column (20).

Carried by 1 Table A entry

UN 3393

Source: ADR 2025 (ECE/TRANS/352), Volume II, section 5.3.2.3.2, X432, page 268.

Paraphrase in FreightUtils' own words, not the official text. Not yet reviewed.

ADR 2027 amendments (accepted, applying from 1 January 2027) are not yet reflected on this page.