ADR hazard number X668

Hazard identification number X668 on the orange plate: highly toxic, corrosive substance that reacts dangerously with water.

Printed in the upper half of the orange-coloured plate above the UN number, X668 identifies a highly toxic, corrosive substance that reacts dangerously with water. A repeated figure means that hazard is intensified. The leading X warns that the substance reacts dangerously with water, so water may be applied only with expert approval.

Digit by digit
Xprefix X: the substance reacts dangerously with water; water may be used on it only with the approval of experts
6toxic, or a risk of infection
6repeated 6: doubling a figure means that hazard (toxic) is intensified
8corrosive

Note. In the 5.3.2.3.2 list this entry carries footnote 1: water is not to be used except with the approval of experts. Number and meaning pairing checked against a second text extraction of the list.

Refers to: 5.3.2.3.1; 5.3.2.2.3; Table A column (20).

Carried by 3 Table A entries

UN 1810 · UN 1834 · UN 1838

Source: ADR 2025 (ECE/TRANS/352), Volume II, section 5.3.2.3.2, X668, page 268.

Paraphrase in FreightUtils' own words, not the official text. Not yet reviewed.

ADR 2027 amendments (accepted, applying from 1 January 2027) are not yet reflected on this page.