ADR packing instruction P520

Heading in ADR: “P520 PACKING INSTRUCTION”

Organic peroxides (5.2) and self-reactive substances (4.1): packing methods OP1-OP8 set per-package quantity limits; metal only for OP7/OP8.

Covers Class 5.2 organic peroxides and Class 4.1 self-reactive substances, with 4.1.1, 4.1.3 and 4.1.7.1 applied. The packing method (OP1 to OP8) assigned in 2.2.41.4 or 2.2.52.4 sets the maximum quantity per package; combination packagings in the listed boxes, drums or jerricans, single drums and jerricans, and composite packagings with plastics inner receptacles may be used. Metal packagings (including inners and outers of combination or composite packagings) are allowed only for OP7 and OP8; glass may be used only as inner packagings of up to 0.5 kg or 0.5 litre; cushioning must not be readily combustible. Substances needing an EXPLOSIVE subsidiary hazard label must also meet 4.1.5.10 and 4.1.5.11. Viscous substances not meeting the liquid definition of 1.2.1 count as solids.

Limits
ValueApplies when
0.5 kg / lOP1 maximum net mass (solids, combination) / contents (liquids)
0.5/10 kgOP2 per inner / per package; not for liquids in litres
5 kg / lOP3 solids or combination / liquids
5/25 kgOP4 per inner / per package; not for liquids in litres
25 kg / 30 l OP5 solids or combination / liquids
50 kg / 60 l OP6 solids or combination / liquids
50 kg / 60 l OP7 solids or combination / liquids
400 kg / 225 l OP8 solids or combination / liquids; jerricans 60 kg or 60 l, boxes 200 kg
Permitted packagings
TypeCodePacking groupsMax capacity (L)Max net mass (kg)
combination: boxes — inner: quantity per packing method4A, 4B, 4N, 4C1, 4C2, 4D, 4F, 4G, 4H1, 4H2———
combination or single: drums1A1, 1A2, 1B1, 1B2, 1G, 1H1, 1H2, 1D———
combination or single: jerricans3A1, 3A2, 3B1, 3B2, 3H1, 3H2———
composite with plastics inner receptacle6HA1, 6HA2, 6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1, 6HH2———

Conditions

special packing provisions referencedPP21, PP22, PP94, PP95

Note. The OP quantity table prints on one scrambled line; values assigned left to right: solids 0.5, 0.5/10, 5, 5/25, 25, 50, 50, 400; liquids 0.5, -, 5, -, 30, 60, 60, 225 (litres). Where two values are given, the first is per inner and the second per package.

Refers to: 4.1.1; 4.1.3; 4.1.7.1; 2.2.41.4; 2.2.52.4; 4.1.5.10; 4.1.5.11; 5.2.2.2.2; 1.2.1; 4.1.7.

Carried by 41 Table A entries

UN 3101 · UN 3102 · UN 3103 · UN 3104 · UN 3105 · UN 3106 · UN 3107 · UN 3108 · UN 3109 · UN 3110 · UN 3111 · UN 3112 · UN 3113 · UN 3114 · UN 3115 · UN 3116 · UN 3117 · UN 3118 · UN 3119 · UN 3120 and 21 more UN numbers

Source: ADR 2025 (ECE/TRANS/352), Volume II, section 4.1.4.1, P520, page 122.

Paraphrase in FreightUtils' own words, not the official text. Not yet reviewed.

ADR 2027 amendments (accepted, applying from 1 January 2027) are not yet reflected on this page.