UN 3251

ISOSORBIDE-5-MONONITRATE

UN 3251 — ADR 2025 Table A: class 4.1, classification code SR1, packing group III, labels 4.1, special provisions 226 638, limited quantity 5 kg, excepted quantity E0, packing instructions P409, transport category 3, tunnel restriction code (D), hazard identification number —.

UNECE ADR 2025, ECE/TRANS/352 · checked 2026-10-28

Table A — ADR 2025 (ECE/TRANS/352), UN 3251
(1) UN No.3251
(2) Name and descriptionISOSORBIDE-5-MONONITRATE
(3a) Class4.1
(3b) Classification codeSR1
(4) Packing groupIII
(5) Labels4.1
(6) Special provisions226 638
(7a) Limited quantities5 kg
(7b) Excepted quantitiesE0
(8) Packaging: packing instructionsP409
(9a) Packaging: special packing provisions—
(9b) Packaging: mixed packing provisionsMP2
(10) Portable tanks and bulk containers: instructions—
(11) Portable tanks and bulk containers: special provisions—
(12) ADR tank: tank code—
(13) ADR tank: special provisions—
(14) Vehicle for tank carriage—
(15) Transport category (Tunnel restriction code)3 (D)
(16) Special provisions for carriage: packages—
(17) Special provisions for carriage: bulk—
(18) Special provisions for carriage: loading, unloading and handlingCV14
(19) Special provisions for carriage: operationS24
(20) Hazard identification No.—

ADR 2027 (accepted) — no change for UN 3251

ADR 2027 was accepted: depositary notification C.N.395.2026 (9 October 2026) records no objection to the amendments proposed by C.N.252.2026. It applies from 1 January 2027, and ADR 2025 may still be applied until 30 June 2027 (1.6.1.1). (C.N.395.2026)

ADR 2027: no Table A change for this entry (checked against ECE/TRANS/WP.15/274, Add.1 and Corr.1). Other parts of ADR 2027 may still affect its carriage.

ADR 2025 remains the edition FreightUtils serves and the one that applies until ADR 2027 takes effect on 1 January 2027; after that, ADR 2025 may still be applied until 30 June 2027 (1.6.1.1).

All ADR 2027 Table A changes →Check a list of UN numbers →

In plain words

Tunnels
Tunnel code (D): in tanks, Prohibited in D, E; in other carriage, Prohibited in D, E. Categories A, B, C. (ADR 8.6.4; from the ADR table itself)
Small-load exemption
Transport category 3: at most 1000 per transport unit under 1.1.3.6, counted ×1 toward the 1,000-point limit (ADR 1.1.3.6.3; from the ADR table itself)
Labels
Labels: model 4.1 (Flammable solids, self-reactive and polymerizing substances, and solid desensitized explosives) (ADR 5.2.2.2.2, label model No. 4.1; paraphrase, not yet reviewed)
Packing
Packing instruction P409: UN 2956, 3242, 3251: fibre drum (50 kg), fibreboard box with one plastics bag (50 kg), or 4G/1G with plastics inners of 5 kg (25 kg). Mixed packing provision MP2: No mixed packing: the goods must be alone in their package. (ADR 4.1.4.1, P409, 4.1.10.4, MP2; paraphrase, not yet reviewed)
Carriage
Loading provision CV14: Shield goods from direct sun and heat in transit; store packages only in cool, well-ventilated places away from heat. Operation provision S24: Chapter 8.4 vehicle supervision applies when the total mass in the vehicle exceeds 100 kg. (ADR 7.5.11, CV14, 8.5, S24; paraphrase, not yet reviewed)

Assembled from FreightUtils' meanings of the Table A codes, not the official text. A statement marked “not yet reviewed” has not yet been checked against ADR by a person.

Class 4.1 — Flammable SolidsPacking Group III
UN 3251Class 4.1 — Flammable SolidsPG III
Packing Group
III
Low danger
Classification Code
SR1
Tunnel Code
(D) meaning →
Code governing tunnel passage
Transport Category
3
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
—
Kemler code
Limited Quantity
5 kg
Max per inner package for LQ relief
Excepted Quantity
E0
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 3
×1 points per kg/L — up to 1,000 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
1,000 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
5 kg
Max per inner packaging for LQ relief (Chapter 3.4)
Excepted Quantity
E0
No excepted-quantity relief for this entry (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Special Provisions
SP 226, SP 638
May alter scope or limits — full text in ADR 2025 Chapter 3.3
Hazard Labels Required
Label 4.1

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

Special Provisions
SP 226SP 638

Refer to ADR 2025 Chapter 3.3 for full text of each provision.

Check if UN 3251 qualifies for 1.1.3.6 exemption
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Other Flammable Solids near UN 3251 (Class 4.1)

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UN 3240
SELF-REACTIVE SOLID TYPE F, TEMP…
UN 3241
2-BROMO-2-NITROPROPANE-1,3-DIOL
UN 3242
AZODICARBONAMIDE
All Class 4.1 UN numbers →
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📅Data: UNECE ADR 2025 (ECE/TRANS/352), via EU Directive 2008/68/EC. Last verified October 2026

ADR reference data only. Classification is the consignor's legal responsibility. Consult a DGSA for compliance decisions.

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