UN 3365

TRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED with not less than 10 % water, by mass

UN 3365 — ADR 2025 Table A: class 4.1, classification code D, packing group I, labels 4.1, special provisions 28, limited quantity 0, excepted quantity E0, packing instructions P406, transport category 1, tunnel restriction code (B), hazard identification number —.

UNECE ADR 2025, ECE/TRANS/352 · checked 2026-10-28

Table A — ADR 2025 (ECE/TRANS/352), UN 3365
(1) UN No.3365
(2) Name and descriptionTRINITROCHLOROBENZENE (PICRYL CHLORIDE), WETTED with not less than 10 % water, by mass
(3a) Class4.1
(3b) Classification codeD
(4) Packing groupI
(5) Labels4.1
(6) Special provisions28
(7a) Limited quantities0
(7b) Excepted quantitiesE0
(8) Packaging: packing instructionsP406
(9a) Packaging: special packing provisionsPP24
(9b) Packaging: mixed packing provisionsMP2
(10) Portable tanks and bulk containers: instructions—
(11) Portable tanks and bulk containers: special provisions—
(12) ADR tank: tank code—
(13) ADR tank: special provisions—
(14) Vehicle for tank carriage—
(15) Transport category (Tunnel restriction code)1 (B)
(16) Special provisions for carriage: packages—
(17) Special provisions for carriage: bulk—
(18) Special provisions for carriage: loading, unloading and handling—
(19) Special provisions for carriage: operationS14
(20) Hazard identification No.—

ADR 2027 (accepted) — no change for UN 3365

ADR 2027 was accepted: depositary notification C.N.395.2026 (9 October 2026) records no objection to the amendments proposed by C.N.252.2026. It applies from 1 January 2027, and ADR 2025 may still be applied until 30 June 2027 (1.6.1.1). (C.N.395.2026)

ADR 2027: no Table A change for this entry (checked against ECE/TRANS/WP.15/274, Add.1 and Corr.1). Other parts of ADR 2027 may still affect its carriage.

ADR 2025 remains the edition FreightUtils serves and the one that applies until ADR 2027 takes effect on 1 January 2027; after that, ADR 2025 may still be applied until 30 June 2027 (1.6.1.1).

All ADR 2027 Table A changes →Check a list of UN numbers →

In plain words

Tunnels
Tunnel code (B): in tanks, Prohibited in B, C, D, E; in other carriage, Prohibited in B, C, D, E. Category A tunnels only. (ADR 8.6.4; from the ADR table itself)
Small-load exemption
Transport category 1: at most 20 per transport unit under 1.1.3.6, counted ×50 toward the 1,000-point limit (ADR 1.1.3.6.3; from the ADR table itself)
Labels
Labels: model 4.1 (Flammable solids, self-reactive and polymerizing substances, and solid desensitized explosives) (ADR 5.2.2.2.2, label model No. 4.1; paraphrase, not yet reviewed)
Packing
Packing instruction P406: Desensitized substances: water-resistant combination, lined single or plastics/metal packagings that keep the wetting agent in and cap pressure at 300 kPa. Special packing provision PP24: UN 2852 and 3364 to 3369 are limited to 500 g per package. Mixed packing provision MP2: No mixed packing: the goods must be alone in their package. (ADR 4.1.4.1, P406, 4.1.4.1, P406, PP24, 4.1.10.4, MP2; paraphrase, not yet reviewed)
Carriage
Operation provision S14: Chapter 8.4 vehicle supervision applies for any amount of these substances. (ADR 8.5, S14; paraphrase, not yet reviewed)

Assembled from FreightUtils' meanings of the Table A codes, not the official text. A statement marked “not yet reviewed” has not yet been checked against ADR by a person.

Class 4.1 — Flammable SolidsPacking Group I
UN 3365Class 4.1 — Flammable SolidsPG I
Packing Group
I
High danger
Classification Code
D
Tunnel Code
(B) meaning →
Code governing tunnel passage
Transport Category
1
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
—
Kemler code
Limited Quantity
0
Max per inner package for LQ relief
Excepted Quantity
E0
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 1
×50 points per kg/L — up to 20 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
20 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
Not permitted
No limited-quantity relief for this entry (Chapter 3.4)
Excepted Quantity
E0
No excepted-quantity relief for this entry (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Special Provisions
SP 28
May alter scope or limits — full text in ADR 2025 Chapter 3.3
Hazard Labels Required
Label 4.1

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

Special Provisions
SP 28

Refer to ADR 2025 Chapter 3.3 for full text of each provision.

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Other Flammable Solids near UN 3365 (Class 4.1)

UN 3364
TRINITROPHENOL (PICRIC ACID), WE…
UN 3366
TRINITROTOLUENE (TNT), WETTED wi…
UN 3367
TRINITROBENZENE, WETTED with not…
UN 3368
TRINITROBENZOIC ACID, WETTED wit…
UN 3369
SODIUM DINITRO-o-CRESOLATE, WETT…
All Class 4.1 UN numbers →
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📅Data: UNECE ADR 2025 (ECE/TRANS/352), via EU Directive 2008/68/EC. Last verified October 2026

ADR reference data only. Classification is the consignor's legal responsibility. Consult a DGSA for compliance decisions.

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