UN 3474

1‑HYDROXYBENZOTRIAZOLE MONOHYDRATE

UN 3474 — ADR 2025 Table A: class 4.1, classification code D, packing group I, labels 4.1, special provisions —, limited quantity 0, excepted quantity E0, packing instructions P406, transport category 1, tunnel restriction code (B), hazard identification number —.

UNECE ADR 2025, ECE/TRANS/352 · checked 2026-10-28

Table A — ADR 2025 (ECE/TRANS/352), UN 3474
(1) UN No.3474
(2) Name and description1‑HYDROXYBENZOTRIAZOLE MONOHYDRATE
(3a) Class4.1
(3b) Classification codeD
(4) Packing groupI
(5) Labels4.1
(6) Special provisions—
(7a) Limited quantities0
(7b) Excepted quantitiesE0
(8) Packaging: packing instructionsP406
(9a) Packaging: special packing provisionsPP48
(9b) Packaging: mixed packing provisionsMP2
(10) Portable tanks and bulk containers: instructions—
(11) Portable tanks and bulk containers: special provisions—
(12) ADR tank: tank code—
(13) ADR tank: special provisions—
(14) Vehicle for tank carriage—
(15) Transport category (Tunnel restriction code)1 (B)
(16) Special provisions for carriage: packages—
(17) Special provisions for carriage: bulk—
(18) Special provisions for carriage: loading, unloading and handling—
(19) Special provisions for carriage: operationS17
(20) Hazard identification No.—

ADR 2027 (accepted) — no change for UN 3474

ADR 2027 was accepted: depositary notification C.N.395.2026 (9 October 2026) records no objection to the amendments proposed by C.N.252.2026. It applies from 1 January 2027, and ADR 2025 may still be applied until 30 June 2027 (1.6.1.1). (C.N.395.2026)

ADR 2027: no Table A change for this entry (checked against ECE/TRANS/WP.15/274, Add.1 and Corr.1). Other parts of ADR 2027 may still affect its carriage.

This entry under ADR 2027 on the API: /api/adr?un=3474&edition=2027 (editions and as_of).

ADR 2025 is the edition that applies until ADR 2027 takes effect on 1 January 2027, and FreightUtils answers on it by default until then; the API answers on ADR 2027 now with edition=2027. After that date, ADR 2025 may still be applied until 30 June 2027 (1.6.1.1).

All ADR 2027 Table A changes →Check a list of UN numbers →

In plain words

Tunnels
Tunnel code (B): in tanks, Prohibited in B, C, D, E; in other carriage, Prohibited in B, C, D, E. Category A tunnels only. (ADR 8.6.4; from the ADR table itself)
Small-load exemption
Transport category 1: at most 20 per transport unit under 1.1.3.6, counted ×50 toward the 1,000-point limit (ADR 1.1.3.6.3; from the ADR table itself)
Labels
Labels: model 4.1 (Flammable solids, self-reactive and polymerizing substances, and solid desensitized explosives) (ADR 5.2.2.2.2, label model No. 4.1; paraphrase, not yet reviewed)
Packing
Packing instruction P406: Desensitized substances: water-resistant combination, lined single or plastics/metal packagings that keep the wetting agent in and cap pressure at 300 kPa. Special packing provision PP48: No metal packagings for the listed substance; small metal fittings such as closures do not make a packaging metal. Mixed packing provision MP2: No mixed packing: the goods must be alone in their package. (ADR 4.1.4.1, P406, 4.1.4.1, P112(c), PP48, 4.1.10.4, MP2; paraphrase, not yet reviewed)
Carriage
Operation provision S17: Chapter 8.4 vehicle supervision applies when the total mass in the vehicle exceeds 1 000 kg. (ADR 8.5, S17; paraphrase, not yet reviewed)

Assembled from FreightUtils' meanings of the Table A codes, not the official text. A statement marked “not yet reviewed” has not yet been checked against ADR by a person.

Class 4.1 — Flammable SolidsPacking Group I
UN 3474Class 4.1 — Flammable SolidsPG I
Packing Group
I
High danger
Classification Code
D
Tunnel Code
(B) meaning →
Code governing tunnel passage
Transport Category
1
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
—
Kemler code
Limited Quantity
0
Max per inner package for LQ relief
Excepted Quantity
E0
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 1
×50 points per kg/L — up to 20 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
20 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
Not permitted
No limited-quantity relief for this entry (Chapter 3.4)
Excepted Quantity
E0
No excepted-quantity relief for this entry (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Hazard Labels Required
Label 4.1

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

Check if UN 3474 qualifies for 1.1.3.6 exemption
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Other Flammable Solids near UN 3474 (Class 4.1)

UN 3527
POLYESTER RESIN KIT, solid base …
UN 3531
POLYMERIZING SUBSTANCE, SOLID, S…
UN 3532
POLYMERIZING SUBSTANCE, LIQUID, …
UN 3533
POLYMERIZING SUBSTANCE, SOLID, T…
UN 3534
POLYMERIZING SUBSTANCE, LIQUID, …
All Class 4.1 UN numbers →
Use this data programmatically
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📅Data: UNECE ADR 2025 (ECE/TRANS/352), via EU Directive 2008/68/EC. Last verified October 2026

ADR reference data only. Classification is the consignor's legal responsibility. Consult a DGSA for compliance decisions.

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