UN 1139

COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining)

Class 3Flammable LiquidsPacking Group I6 variants
UN 1139 has 6 classification variants in ADR 2025 — different hazard divisions or descriptions for the same UN number. Each variant may have different transport requirements.
UN 1139Class 3 — Flammable LiquidsPG IVariant 1 of 6
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining)
Packing Group
I
High danger
Classification Code
F1
Tunnel Code
(D/E) meaning →
Code governing tunnel passage
Transport Category
1
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
33
Kemler code
Limited Quantity
500 ml
Max per inner package for LQ relief
Excepted Quantity
E3
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 1
×50 points per kg/L — up to 20 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
20 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
500 ml
Max per inner packaging for LQ relief (Chapter 3.4)
Excepted Quantity
E3
Max 30 ml/g per inner, 300 ml/g per outer package (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Hazard Labels Required
Label 3

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

UN 1139Class 3 — Flammable LiquidsPG IIVariant 2 of 6
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C more than 110 kPa)
Packing Group
II
Medium danger
Classification Code
F1
Tunnel Code
(D/E) meaning →
Code governing tunnel passage
Transport Category
2
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
33
Kemler code
Limited Quantity
5 L
Max per inner package for LQ relief
Excepted Quantity
E2
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 2
×3 points per kg/L — up to 333 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
333 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
5 L
Max per inner packaging for LQ relief (Chapter 3.4)
Excepted Quantity
E2
Max 30 ml/g per inner, 500 ml/g per outer package (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Special Provisions
SP 640C
May alter scope or limits — full text in ADR 2025 Chapter 3.3
Hazard Labels Required
Label 3

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

Special Provisions
SP 640C

Refer to ADR 2025 Chapter 3.3 for full text of each provision.

UN 1139Class 3 — Flammable LiquidsPG IIVariant 3 of 6
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (vapour pressure at 50 °C not more than 110 kPa)
Packing Group
II
Medium danger
Classification Code
F1
Tunnel Code
(D/E) meaning →
Code governing tunnel passage
Transport Category
2
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
33
Kemler code
Limited Quantity
5 L
Max per inner package for LQ relief
Excepted Quantity
E2
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 2
×3 points per kg/L — up to 333 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
333 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
5 L
Max per inner packaging for LQ relief (Chapter 3.4)
Excepted Quantity
E2
Max 30 ml/g per inner, 500 ml/g per outer package (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Special Provisions
SP 640D
May alter scope or limits — full text in ADR 2025 Chapter 3.3
Hazard Labels Required
Label 3

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

Special Provisions
SP 640D

Refer to ADR 2025 Chapter 3.3 for full text of each provision.

UN 1139Class 3 — Flammable LiquidsPG IIIVariant 4 of 6
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining)
Packing Group
III
Low danger
Classification Code
F1
Tunnel Code
(D/E) meaning →
Code governing tunnel passage
Transport Category
3
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
30
Kemler code
Limited Quantity
5 L
Max per inner package for LQ relief
Excepted Quantity
E1
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 3
×1 points per kg/L — up to 1,000 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
1,000 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
5 L
Max per inner packaging for LQ relief (Chapter 3.4)
Excepted Quantity
E1
Max 30 ml/g per inner, 1,000 ml/g per outer package (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Hazard Labels Required
Label 3

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

UN 1139Class 3 — Flammable LiquidsPG IIIVariant 5 of 6
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C more than 110 kPa)
Packing Group
III
Low danger
Classification Code
F1
Tunnel Code
(E) meaning →
Code governing tunnel passage
Transport Category
3
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
Kemler code
Limited Quantity
5 L
Max per inner package for LQ relief
Excepted Quantity
E1
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 3
×1 points per kg/L — up to 1,000 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
1,000 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
5 L
Max per inner packaging for LQ relief (Chapter 3.4)
Excepted Quantity
E1
Max 30 ml/g per inner, 1,000 ml/g per outer package (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Hazard Labels Required
Label 3

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

UN 1139Class 3 — Flammable LiquidsPG IIIVariant 6 of 6
COATING SOLUTION (includes surface treatments or coatings used for industrial or other purposes such as vehicle under coating, drum or barrel lining) (having a flash-point below 23 °C and viscous according to 2.2.3.1.4) (vapour pressure at 50 °C not more than 110 kPa)
Packing Group
III
Low danger
Classification Code
F1
Tunnel Code
(E) meaning →
Code governing tunnel passage
Transport Category
3
For the 1,000-point rule (0 = highest restriction)
Hazard ID No.
Kemler code
Limited Quantity
5 L
Max per inner package for LQ relief
Excepted Quantity
E1
EQ code for excepted quantity relief
Thresholds — why, not just the verdict
Transport Category
Category 3
×1 points per kg/L — up to 1,000 kg/L of this substance alone stays under the 1,000-point threshold
Per-substance max
1,000 kg/L
Per-substance maximum for 1.1.3.6 relief (1.1.3.6.3)
Limited Quantity
5 L
Max per inner packaging for LQ relief (Chapter 3.4)
Excepted Quantity
E1
Max 30 ml/g per inner, 1,000 ml/g per outer package (Chapter 3.5)
Tunnel Code
Governs which tunnel categories the load may pass
Hazard Labels Required
Label 3

These labels must be displayed on packages and vehicle placards in accordance with ADR 2025.

Check if UN 1139 qualifies for 1.1.3.6 exemption
Calculate small load points and check exemption thresholds
Open calculator →

Other Flammable Liquids (Class 3)

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ACETAL
UN 1089
ACETALDEHYDE
UN 1090
ACETONE
UN 1091
ACETONE OILS
UN 1093
ACRYLONITRILE, STABILIZED
Use this data programmatically
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📅Data: UNECE ADR 2025 (ECE/TRANS/352), via EU Directive 2008/68/EC. Last verified August 2026

ADR reference data only. Classification is the consignor's legal responsibility. Consult a DGSA for compliance decisions.

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