Special provisions

Provisions attached to an entry that extend, limit or lift the rules for it — some take goods out of ADR altogether. These codes appear in Table A column 6; ADR sets them out in section 3.3.1 of ADR 2025 (ECE/TRANS/352). 331 codes are in use, 0 reviewed. Each meaning below is a paraphrase in FreightUtils' own words, not the official text.

• 274 · 767 rows
  The rules of 3.1.2.8 apply: the proper shipping name has to be completed with the technical name.
• 61 · 165 rows
  The technical name added to the proper shipping name must be the ISO common name, a WHO-listed name or the active substance name.
• 662 · 105 rows
  Non-Chapter 6.2 cylinders used only aboard ships or aircraft may go for filling or inspection and return, with a document statement.
• 648 · 91 rows
  Articles impregnated with this pesticide (fibreboard, paper strips, cotton wool, plastic sheet) in hermetic wrappings are not subject to ADR.
• 386 · 57 rows
  Polymerizing substances: temperature control rules apply when used; chemical stabilization must prevent polymerization at 50 °C (portable tanks 45 °C).
• 676 · 57 rows
  Polymerizing substances carried for disposal or recycling may skip SP 386 temperature control if checked, quick, shaded, < 45 °C and ≤ 1000 l.
• 43 · 55 rows
  When offered as pesticides, these substances go under the matching pesticide entry and pesticide rules.
• 354 · 51 rows
  The substance is toxic by inhalation.
• 28 · 40 rows
  Class 3 or 4.1 carriage allowed only if packing keeps the diluent at or above the stated percentage throughout carriage.
• 178 · 37 rows
  Last-resort designation: only if Table A has no fitting entry, and only once the competent authority of the origin country approves.
• 601 · 31 rows
  Ready-for-use medicines packaged for retail sale or personal/household use are not subject to ADR.
• 279 · 28 rows
  The class or packing group shown rests on practical human experience, not on a strict reading of the ADR criteria.
• 392 · 26 rows
  Vehicle fuel gas containment systems moved for disposal, recycling, repair, inspection, maintenance or to assembly are relieved of 4.1.4.1 and Chapter 6.2.
• 163 · 23 rows
  Not for substances named in Table A; substances here may hold up to 20 % nitrocellulose of at most 12.6 % nitrogen (dry mass).
• 640C · 22 rows
  SP 640 letter C: in ADR tanks the document shows "Special provision 640C"; on Class 3 PG II entries it marks vapour pressure at 50 °C above 110 kPa.
• 640D · 22 rows
  SP 640 letter D: in ADR tanks the document shows "Special provision 640D"; on Class 3 PG II entries it marks vapour pressure at 50 °C ≤ 110 kPa.
• 327 · 21 rows
  Waste aerosols and gas cartridges may travel as UN 1950/2037 for recycling or disposal, packed per P207/P003 or LP200; pierced non-toxic ones are exempt.
• 344 · 21 rows
  The requirements of 6.2.6 must be complied with.
• 122 · 20 rows
  Subsidiary hazards, control and emergency temperatures and generic UN numbers for organic peroxides are listed in 2.2.52.4, IBC520 and T23.
• 194 · 20 rows
  2.2.41.4 lists control and emergency temperatures and generic UN numbers for each assigned self-reactive substance.
• 172 · 19 rows
  Radioactive material with subsidiary hazards: packing group, extra labels, placards, name and document entries follow the subsidiary hazard.
• 367 · 18 rows
  Paint and printing ink packed with their related material may be documented under the related-material shipping name.
• 266 · 15 rows
  With less alcohol, water or phlegmatizer than specified, carriage only by specific competent authority authorization.
• 315 · 14 rows
  Not to be used for Class 6.1 substances meeting the packing group I inhalation toxicity criteria of 2.2.61.1.8.
• 664 · 14 rows
  Tank-vehicles and demountable tanks for this substance may carry additive devices under set construction, approval, use, test and document rules.
• 310 · 13 rows
  Low-production (≤ 100) or prototype cells and batteries carried for testing: partial 2.2.9.1.7.1 tests, P910/LP905, and a document statement.
• 347 · 13 rows
  Entry usable only if test series 6(d) shows any hazardous effects of functioning stay inside the package.
• 190 · 12 rows
  Aerosols need protection against accidental discharge; aerosols of 50 ml or less with only non-toxic constituents are not subject to ADR.
• 317 · 12 rows
  The term 'fissile-excepted' covers only fissile material and packages excepted under 2.2.7.2.3.5.
• 562 · 12 rows
  Organometallic compounds go to Class 4.2 if spontaneously combustible, or to Class 4.3 if flammable and water-reactive.
• 625 · 12 rows
  Packages of these articles must be clearly marked "UN 1950 AEROSOLS".
• 303 · 9 rows
  Each receptacle takes the classification code of the gas or gas mixture it holds, determined under 2.2.2.
• 325 · 9 rows
  Non-fissile or fissile-excepted uranium hexafluoride is classified under UN 2978.
• 540 · 9 rows
  Hafnium, titanium or zirconium powder wetted with ≥ 25 % water (UN 1326, 1352, 1358) is Class 4.1.
• 181 · 8 rows
  Packages need an explosive (model No. 1) label unless the origin authority waives it on test evidence for that packaging.
• 182 · 8 rows
  Defines alkali metals as lithium, sodium, potassium, rubidium and caesium.
• 314 · 8 rows
  Substances that can decompose exothermically when hot: keep out of direct sun, away from heat sources, in well-ventilated areas.
• 326 · 8 rows
  Fissile uranium hexafluoride is classified under UN 2977.
• 378 · 8 rows
  Radiation detectors holding this gas in non-refillable receptacles outside Chapter 6.2/P200 may travel if pressure, size, burst and packing limits are met.
• 593 · 8 rows
  Gas used to cool non-dangerous goods in P203(6)-compliant open cryogenic double-wall receptacles is outside ADR except 5.5.3.
• 667 · 8 rows
  Damaged vehicles, engines or machinery with lithium or sodium ion batteries: 2.2.9.1.7.1/.2 do not apply; carry under SP 363/666 or remove per SP 376.
• 669 · 8 rows
  A trailer with fuel- or battery-powered equipment, carried as a load, goes under UN 3166, 3171, 3556, 3557 or 3558 if liquid fuel ≤ 500 l.
• 183 · 7 rows
  Defines alkaline earth metals as magnesium, calcium, strontium and barium.
• 617 · 7 rows
  Packages must be marked with the explosive's commercial name as well as its type.
• 650 · 7 rows
  Paint waste may go as UN 1263 PG II or UN 3082, with extra options for packing, flexible IBCs, bulk and a set document description.
• 188 · 6 rows
  Small lithium and sodium ion cells and batteries escape most of ADR when the size, packing, marking, drop-test and mass limits are all met.
• 210 · 6 rows
  Toxins from plant, animal or bacterial sources that contain, or are contained in, infectious substances are Class 6.2.
• 221 · 6 rows
  Substances under this entry must not be packing group I.
• 230 · 6 rows
  Lithium cells and batteries may use this entry if they meet 2.2.9.1.7.1; sodium ion ones if they meet 2.2.9.1.7.2.
• 318 · 6 rows
  Add the technical name to the shipping name; for suspected but unknown Category A substances, show the suspected Category A wording in brackets.
• 376 · 6 rows
  Damaged or defective lithium and sodium ion cells and batteries: assessment, packing under P908/LP904 or P911/LP906, special marks and a document statement.
• 377 · 6 rows
  Lithium and sodium ion batteries sent for disposal or recycling may be packed to P909, are exempt from the 2.2.9.1.7 test conditions and need a special mark.
• 563 · 6 rows
  Selenic acid, UN 1905, is classified in Class 8.
• 614 · 6 rows
  TCDD at concentrations highly toxic under the 2.2.61.1 criteria is prohibited from carriage.
• 659 · 6 rows
  Substances assigned PP86 or TP7 (air must be removed from vapour space) may not use this entry; carry them under their own UN numbers.
• 677 · 6 rows
  Damaged or defective cells/batteries liable to react dangerously in carriage are transport category 0, shown in the document.
• 295 · 5 rows
  Individual batteries need no marks or labels if the pallet carries the right mark and label.
• 328 · 5 rows
  Fuel cell cartridges, alone or with equipment: leak-proof design, 100 kPa pressure test for liquid fuels, 1.2 m drop test; batteries consigned too.
• 340 · 5 rows
  Chemical, first aid and polyester resin kits within column (7b) inner limits may use Chapter 3.5; Class 5.2 in such kits gets code E2.
• 388 · 5 rows
  Sorts vehicles and equipment into UN 3166, 3171, 3556-3558, 3091, 3481 and 3536 by power source; integral dangerous components are exempt.
• 506 · 5 rows
  Pyrophoric alkaline earth metals and alloys are Class 4.2; magnesium (> 50 %) pellets, turnings or ribbons (UN 1869) are Class 4.1.
• 524 · 5 rows
  Finished zirconium products (UN 2858) 18 µm thick or more are Class 4.1.
• 592 · 5 rows
  Empty uncleaned packagings, IBCs, large packagings, tanks and small containers that held this substance are not subject to ADR.
• 645 · 5 rows
  The column (3b) classification code may be used only with prior written competent-authority approval (classification approval certificate).
• 666 · 5 rows
  Vehicles and battery-powered equipment carried as a load, with their operating dangerous goods, escape the rest of ADR if valves are closed etc.
• 674 · 5 rows
  Over-moulded cylinders: an alternative periodic inspection method using destructive sample testing, traceability and statistical evaluation.
• 198 · 4 rows
  Nitrocellulose solutions with 20 % nitrocellulose or less may travel under the paint, perfumery product or printing ink entries.
• 236 · 4 rows
  Polyester resin kits: Class 3 or 4.1 base (PG II/III) plus type D, E or F peroxide activator without temperature control; LQ limit applies to base.
• 290 · 4 rows
  Radioactive material that also meets another class: excepted-quantity rules, or classification by the predominant subsidiary hazard above 3.5.1.2 limits.
• 293 · 4 rows
  Defines the four kinds of matches: fusee, safety, strike anywhere and wax vesta.
• 305 · 4 rows
  Not subject to ADR at concentrations of 50 mg/kg or less.
• 336 · 4 rows
  Air limit: a single package of non-combustible LSA-II or LSA-III solid may hold at most 3 000 A2 of activity.
• 337 · 4 rows
  By air, Type B(U) and B(M) packages are capped: as certified for low dispersible material, 3 000 A1 or 100 000 A2 for special form, 3 000 A2 otherwise.
• 348 · 4 rows
  Lithium batteries made after 31 December 2011 and sodium ion batteries made after 31 December 2025 must show their Wh rating on the case.
• 357 · 4 rows
  Crude oil with hydrogen sulphide posing an inhalation hazard is consigned as UN 3494 PETROLEUM SOUR CRUDE OIL, FLAMMABLE, TOXIC.
• 387 · 4 rows
  Batteries with both lithium metal and lithium ion cells go to UN 3090 or 3091; under SP 188 they are capped at 1.5 g lithium and 10 Wh.
• 393 · 4 rows
  Nitrocellulose must pass the Bergmann-Junk or methyl violet paper test (Manual Appendix 10); type 3 (c) tests are not required.
• 394 · 4 rows
  Nitrocellulose must pass the Bergmann-Junk or methyl violet paper test of Manual of Tests and Criteria Appendix 10.
• 401 · 4 rows
  Sodium battery assignment: organic electrolyte to UN 3551/3552, aqueous alkali electrolyte to UN 2795, metallic sodium or sodium alloy to UN 3292.
• 406 · 4 rows
  May be carried as limited quantities in pressure receptacles of up to 1 000 ml meeting P200, with test pressure × capacity ≤ 15.2 MPa·l, packed alone.
• 511 · 4 rows
  Mercuric nitrate, mercurous nitrate and thallium nitrate are Class 6.1; thorium and uranyl nitrates are Class 7.
• 521 · 4 rows
  Solid chlorites and hypochlorites are Class 5.1.
• 530 · 4 rows
  Aqueous hydrazine solution with ≤ 37 % hydrazine by mass (UN 3293) is Class 6.1.
• 531 · 4 rows
  Mixtures flashing below 23 °C with > 55 % nitrocellulose, or ≤ 55 % with > 12.6 % nitrogen, are Class 1 (UN 0340/0342) or 4.1 (UN 2555-2557).
• 598 · 4 rows
  New and used storage batteries are outside ADR when secured, clean of acid/alkali traces and short-circuit protected as listed.
• 602 · 4 rows
  Phosphorus sulphides containing yellow or white phosphorus are prohibited from carriage.
• 632 · 4 rows
  The substance is regarded as pyrophoric (spontaneously flammable).
• 638 · 4 rows
  Covers substances related to Class 4.1 self-reactive substances (2.2.41.1.19).
• 655 · 4 rows
  Breathing-apparatus cylinders built to Directive 97/23/EC or 2014/68/EU may go without Chapter 6.2 if inspected per 6.2.1.6.1 and P200 intervals.
• 23 · 3 rows
  Explanatory: the substance is flammable only under extreme fire conditions in confined spaces.
• 47 · 3 rows
  Ferricyanides and ferrocyanides are not subject to ADR.
• 66 · 3 rows
  Cinnabar is not subject to ADR.
• 103 · 3 rows
  Ammonium nitrites, and any inorganic nitrite mixed with an ammonium salt, may not be carried.
• 113 · 3 rows
  Carriage of chemically unstable mixtures is prohibited.
• 144 · 3 rows
  Aqueous solutions with 24 % alcohol by volume or less are not subject to ADR.
• 191 · 3 rows
  Small receptacles of 50 ml or less holding only non-toxic constituents are not subject to ADR.
• 300 · 3 rows
  Fish meal, fish scrap and krill meal may not be loaded above 35 °C, or above ambient plus 5 °C if that is higher.
• 343 · 3 rows
  For crude oil whose hydrogen sulphide vapours can be an inhalation hazard; packing group set by flammability and inhalation hazard.
• 350 · 3 rows
  Ammonium bromate, its water solutions, and bromate-ammonium salt mixtures are prohibited from carriage.
• 351 · 3 rows
  Ammonium chlorate, its water solutions, and chlorate-ammonium salt mixtures are prohibited from carriage.
• 353 · 3 rows
  Ammonium permanganate, its water solutions, and permanganate-ammonium salt mixtures are prohibited from carriage.
• 360 · 3 rows
  Vehicles powered only by lithium or sodium ion batteries go to UN 3556/3557/3558; CTU-installed lithium batteries for external power go to UN 3536.
• 363 · 3 rows
  Fuel-powered engines and machinery (UN 3528/3529/3530): only these conditions apply; empty units are exempt; labels, placards and documents scale with fuel.
• 364 · 3 rows
  The article may use Chapter 3.4 limited quantities only if its package can pass test series 6(d), as decided by the competent authority.
• 408 · 3 rows
  Entry only for aqueous TMAH solutions with ≤ 1 % other constituents; surfactant formulations go to UN 2927 PG I or II by TMAH content.
• 504 · 3 rows
  Hydrated potassium and sodium sulphide (≥ 30 % water) and sodium hydrosulphide (≥ 25 % water) are Class 8.
• 515 · 3 rows
  Chloropicrin mixed with methyl bromide (UN 1581) or methyl chloride (UN 1582) is Class 2.
• 523 · 3 rows
  Anhydrous potassium and sodium sulphide (and hydrates < 30 % water) and sodium hydrosulphide (< 25 % water) are Class 4.2.
• 525 · 3 rows
  Inorganic cyanide solutions: PG I above 30 % cyanide ion, PG II above 3 % to 30 %, PG III above 0.3 % to 3 %.
• 529 · 3 rows
  Mercury fulminate wetted with ≥ 20 % water or alcohol/water (UN 0135) is Class 1; calomel (UN 2025) is Class 6.1.
• 541 · 3 rows
  Nitrocellulose mixtures below the stated water, alcohol or plasticizer content are Class 1.
• 544 · 3 rows
  Anhydrous dimethylamine, ethylamine, anhydrous methylamine and anhydrous trimethylamine (UN 1032, 1036, 1061, 1083) are Class 2.
• 548 · 3 rows
  Chlorosilanes that give off flammable gas in contact with water are Class 4.3.
• 551 · 3 rows
  Solutions of these isocyanates with a flash-point below 23 °C are Class 3.
• 557 · 3 rows
  Pyrophoric metal dust and powder are Class 4.2.
• 558 · 3 rows
  Pyrophoric metals and alloys are Class 4.2; non-water-reactive, non-self-heating but readily ignitable ones are Class 4.1.
• 564 · 3 rows
  Vanadium oxytrichloride (UN 2443), vanadium tetrachloride (UN 2444) and vanadium trichloride (UN 2475) are Class 8.
• 586 · 3 rows
  Hafnium, titanium, zirconium powders need visible excess water; coarse wetted powders (≥ 53 µm mechanical, ≥ 840 µm chemical) are outside ADR.
• 596 · 3 rows
  Cadmium pigments such as cadmium sulphides, sulphoselenides and fatty-acid salts are not subject to ADR.
• 636 · 3 rows
  Small waste lithium and sodium ion cells/batteries going to sorting, disposal or recycling escape most of ADR under P909, a 333 kg cap and marking.
• 643 · 3 rows
  Asphalt mixed with stone or aggregate is released from the Class 9 requirements.
• 652 · 3 rows
  Aviation-approved hot-air balloon fuel receptacles in service before 1 July 2004 may go by road under listed conditions without Chapter 6.2.
• 657 · 3 rows
  Use this entry for the technically pure substance only; LPG mixtures go under UN 1965 or UN 1075 with 2.2.2.3 note 2.
• 670 · 3 rows
  Lithium/sodium ion batteries in household equipment collected for recycling or disposal escape most of ADR, subject to (a) or (b) conditions.
• 45 · 2 rows
  Antimony sulphides and oxides with arsenic of 0.5 % or less of total mass are not subject to ADR.
• 105 · 2 rows
  Nitrocellulose matching UN 2556 or UN 2557 descriptions may be classified in Class 4.1.
• 138 · 2 rows
  p-Bromobenzyl cyanide is not subject to ADR.
• 152 · 2 rows
  Classification varies with particle size and packaging; no borderlines are set, so classify under 2.2.1.
• 168 · 2 rows
  Asbestos bound in a binder so no hazardous respirable fibres escape is outside ADR; other asbestos articles too if packed to prevent escape.
• 169 · 2 rows
  Solid phthalic anhydride and tetrahydrophthalic anhydrides with 0.05 % maleic anhydride or less are outside ADR; hot molten form goes to UN 3256.
• 177 · 2 rows
  Barium sulphate is not subject to ADR.
• 203 · 2 rows
  Not to be used for polychlorinated biphenyls, liquid (UN 2315) or solid (UN 3432).
• 219 · 2 rows
  GMMOs and GMOs packed and marked to P904 are free of other ADR requirements, unless they meet Class 6.1 or 6.2 criteria.
• 220 · 2 rows
  Show in brackets after the proper shipping name only the technical name of the flammable liquid component.
• 224 · 2 rows
  Unless tests show frozen sensitivity is no greater than liquid, the substance must stay liquid in normal carriage and not freeze above -15 °C.
• 244 · 2 rows
  Entry includes e.g. aluminium dross, skimmings, spent cathodes, spent potliner and aluminium salt slags.
• 270 · 2 rows
  Water solutions of Class 5.1 inorganic solid nitrates fall outside Class 5.1 if at the coldest carriage temperature they are at most 80 % saturated.
• 272 · 2 rows
  Carriage under Class 4.1 only with specific competent authority authorization; otherwise see UN 0143 or UN 0150.
• 289 · 2 rows
  Safety devices, electrically initiated or pyrotechnic, already fitted in vehicles, vessels, aircraft or finished components are outside ADR.
• 296 · 2 rows
  Life-saving appliances (UN 2990 self-inflating, UN 3072 not): permitted contents listed; small gas-only packs up to 40 kg gross are outside ADR.
• 306 · 2 rows
  Only for substances too insensitive for Class 1 under test series 2 of the Manual of Tests and Criteria.
• 309 · 2 rows
  For non-sensitized ammonium nitrate emulsions, suspensions and gels (ANE) meant to become Type E blasting explosives; test series 8 and approval needed.
• 311 · 2 rows
  Carriage only with competent authority approval based on Manual Part I tests; packaging must keep the diluent at or above the approved percentage.
• 319 · 2 rows
  Substances packed, and packages marked, according to P650 are subject to no other ADR requirements.
• 322 · 2 rows
  Packing group III applies when carried as non-friable tablets.
• 334 · 2 rows
  A fuel cell cartridge may hold an activator if two independent means stop it mixing with the fuel in carriage.
• 335 · 2 rows
  Non-ADR solids mixed with environmentally hazardous liquids or solids go under UN 3077 if no free liquid is visible; otherwise UN 3082.
• 342 · 2 rows
  Ethylene oxide glass ampoules for sterilizers (< 30 ml each, ≤ 300 ml per outer) may go as excepted quantities despite E0, with three safeguards.
• 365 · 2 rows
  Manufactured instruments and articles containing mercury or gallium belong under UN 3506 or UN 3554.
• 366 · 2 rows
  Manufactured instruments and articles with no more than 1 kg of mercury or gallium are outside ADR.
• 368 · 2 rows
  Non-fissile or fissile-excepted uranium hexafluoride is classified under UN 3507 or UN 2978.
• 375 · 2 rows
  Not subject to further ADR provisions when in packagings of 5 l (liquids) or 5 kg (solids) or less per single or inner packaging meeting the general rules.
• 379 · 2 rows
  Ammonia adsorbed or absorbed on a solid in dispensing systems or their receptacles is exempt from ADR if pressure, content and receptacle conditions are met.
• 390 · 2 rows
  Packages mixing lithium batteries contained in and packed with equipment: marked UN 3091/3481 and documented as PACKED WITH EQUIPMENT.
• 400 · 2 rows
  Short-circuited sodium ion cells and batteries, alone or with equipment, are exempt from ADR when (a) to (f) are met.
• 407 · 2 rows
  Fire suppressant dispersing devices must meet 1.4S criteria (test series 6 (c)) and be safed; Class 9 UN 3559 needs extra conditions and authority approval.
• 502 · 2 rows
  Nitrocellulose-based self-heating plastics n.o.s. (UN 2006) and celluloid scrap (UN 2002) are Class 4.2.
• 503 · 2 rows
  Molten white phosphorus is UN 2447.
• 508 · 2 rows
  Titanium hydride (UN 1871) and zirconium hydride (UN 1437) are Class 4.1; aluminium borohydride (UN 2870) is Class 4.2.
• 512 · 2 rows
  Antimony pentachloride liquid and solution, antimony pentafluoride and antimony trichloride (UN 1730-1733) are Class 8.
• 513 · 2 rows
  Barium compounds by class: azide dry or < 50 % water Class 1, wetted ≥ 50 % Class 4.1; pyrophoric alloys 4.2; oxidizers 5.1; cyanide and oxide 6.1.
• 514 · 2 rows
  Beryllium nitrate (UN 2464) is Class 5.1.
• 517 · 2 rows
  Sodium, potassium and ammonium fluorides and fluorosilicates (UN 1690, 1812, 2505, 2674, 2856, 3415, 3422) are Class 6.1.
• 518 · 2 rows
  Anhydrous chromium trioxide (solid chromic acid, UN 1463) is Class 5.1.
• 519 · 2 rows
  Anhydrous hydrogen bromide (UN 1048) is Class 2.
• 520 · 2 rows
  Anhydrous hydrogen chloride (UN 1050) is Class 2.
• 552 · 2 rows
  Self-igniting powdered or flammable metals and alloys are Class 4.2; those emitting flammable gas with water are Class 4.3.
• 554 · 2 rows
  Metal hydrides emitting flammable gas with water are Class 4.3; aluminium borohydride and in devices (UN 2870) are Class 4.2.
• 555 · 2 rows
  Non-toxic, non-spontaneously combustible metal dust and powder that emits flammable gas with water is Class 4.3.
• 560 · 2 rows
  Elevated temperature liquid n.o.s. at 100 °C or above (incl. molten metals and salts), below any flashpoint, is Class 9, UN 3257.
• 561 · 2 rows
  Chloroformates whose main hazard is corrosivity are Class 8.
• 565 · 2 rows
  Unspecified medical, veterinary or research waste unlikely to hold Class 6.2 goes under this entry; decontaminated waste escapes Class 6.2.
• 583 · 2 rows
  Covers LPG-type mixtures A, A01, A02, A0, A1, B1, B2, B and C, defined by vapour pressure at 70 °C and density at 50 °C.
• 584 · 2 rows
  Gas in sound metal capsules (sodors, sparklets) is outside ADR at ≤ 25 g per capsule, ≤ 0.75 g/cm³ and ≤ 0.5 % air.
• 587 · 2 rows
  Barium stearate and barium titanate are not subject to ADR.
• 588 · 2 rows
  Solid hydrated aluminium bromide and aluminium chloride are not subject to ADR.
• 594 · 2 rows
  Fire extinguishers (UN 1044) and pressurized pneumatic/hydraulic articles (UN 3164) built to national rules are exempt when packed as stated.
• 603 · 2 rows
  Anhydrous hydrogen cyanide not fitting UN 1051 or UN 1614 is prohibited; < 3 % water, pH 2.5 ± 0.5, clear counts as stable.
• 633 · 2 rows
  Packages and small containers need a "Keep away from any source of ignition" mark, in the forwarding country's language plus EN/FR/DE.
• 635 · 2 rows
  No model No. 9 label needed on packages unless the article is fully enclosed so it cannot readily be identified.
• 637 · 2 rows
  GMMOs/GMOs not dangerous to people or animals are outside ADR if authorised by origin, transit and destination authorities.
• 665 · 2 rows
  Unground hard coal, coke and anthracite meeting Class 4.2 PG III criteria are not subject to ADR.
• 668 · 2 rows
  Hot road-marking substances and crack-repair bitumen are outside ADR if only Class 9, boiler skin ≤ 70 °C, closed, ≤ 3 000 l.
• 675 · 2 rows
  Packages of these goods may not be loaded together with Class 1 goods other than 1.4S.
• 678 · 2 rows
  Free-asbestos waste (UN 2212/2590) of listed kinds may go in bulk under Chapter 7.3, site to disposal, as a full load.
• 16 · 1 row
  Explosive samples for testing, classification, R&D, quality control or commercial use move as the competent authority directs, with mass caps.
• 32 · 1 row
  Not subject to ADR in any form other than the one described in the entry.
• 37 · 1 row
  Not subject to ADR when the substance is coated.
• 38 · 1 row
  Not subject to ADR when calcium carbide content is 0.1 % or less.
• 39 · 1 row
  Not subject to ADR when silicon content is below 30 % or is 90 % or more.
• 48 · 1 row
  Carriage prohibited when the substance contains more than 20 % hydrocyanic acid.
• 59 · 1 row
  Not subject to ADR when magnesium content is 50 % or less.
• 60 · 1 row
  Carriage prohibited when the concentration is above 72 %.
• 62 · 1 row
  Not subject to ADR when sodium hydroxide content is 4 % or less.
• 65 · 1 row
  Aqueous hydrogen peroxide below 8 % is not subject to ADR.
• 119 · 1 row
  Refrigerating machines and components are outside ADR if they hold under 12 kg of group A or O gas or under 12 litres of ammonia solution.
• 127 · 1 row
  Another inert material or mixture may replace the named phlegmatizer if its phlegmatizing properties are identical.
• 131 · 1 row
  The phlegmatized substance must be significantly less sensitive than dry PETN.
• 135 · 1 row
  Dihydrated sodium dichloroisocyanurate is not Class 5.1 and is outside ADR unless it meets another class.
• 141 · 1 row
  Products heat-treated enough to pose no hazard in carriage are not subject to ADR.
• 142 · 1 row
  Solvent-extracted soya bean meal with at most 1.5 % oil and 11 % moisture, essentially free of flammable solvent, is not subject to ADR.
• 145 · 1 row
  PG III alcoholic beverages carried in receptacles up to 250 litres are outside ADR.
• 153 · 1 row
  Entry usable only if tests show the substance does not burn or self-ignite with water and the evolved gas mix is non-flammable.
• 193 · 1 row
  Only for ammonium nitrate based compound fertilizers classified by Manual of Tests and Criteria Part III Section 39; those meeting it are outside ADR.
• 196 · 1 row
  Only non-explosive, thermally stable formulations (SADT 60 °C or more for 50 kg) may use this entry; others go to Class 5.2.
• 199 · 1 row
  Lead compounds with 5 % or less solubility in the 0.07M HCl test (ISO 3711) count as insoluble and are outside ADR unless another class applies.
• 201 · 1 row
  Lighters and refills: country-of-filling rules, discharge protection, 85 % fill at 15 °C, sealed valves; max 10 g (lighters) or 65 g (refills) LPG.
• 205 · 1 row
  Not to be used for UN 3155 pentachlorophenol.
• 207 · 1 row
  Plastics moulding compounds may be made of polystyrene, poly(methyl methacrylate) or another polymer.
• 208 · 1 row
  Commercial calcium nitrate fertilizer (double salt, ≤ 10 % ammonium nitrate, ≥ 12 % water of crystallization) is not subject to ADR.
• 215 · 1 row
  Only for technically pure azodicarbonamide or formulations with SADT above 75 °C; mixtures ≤ 35 % with ≥ 65 % inert are outside ADR.
• 216 · 1 row
  Non-regulated solids mixed with flammable liquids may use this entry without Class 4.1 testing if no free liquid is visible; small sealed packets exempt.
• 217 · 1 row
  Non-regulated solids mixed with toxic liquids may use this entry without Class 6.1 testing if no free liquid is visible; not for packing group I liquids.
• 218 · 1 row
  Non-regulated solids mixed with corrosive liquids may use this entry without Class 8 testing if no free liquid is visible at loading or closing.
• 225 · 1 row
  Fire extinguishers may contain actuating cartridges (1.4C/1.4S) up to 3.2 g propellant per unit and stay Class 2; covers portable to wheeled units.
• 226 · 1 row
  Formulations with 30 % or more of a non-volatile, non-flammable phlegmatizer fall outside ADR.
• 227 · 1 row
  Urea nitrate phlegmatized with water and inorganic inert material: at most 75 % by mass and must pass Series 1 type (a) without detonation.
• 228 · 1 row
  Mixtures that do not meet the flammable gas criteria go under UN 3163.
• 235 · 1 row
  Covers vehicle, vessel or aircraft safety articles containing Class 1 explosives, e.g. air bag inflators and seat-belt pretensioners.
• 237 · 1 row
  Membrane filter materials must not propagate detonation in test series 1 (a); authority may exempt nitrocellulose filters from Class 4.1 on burning tests.
• 238 · 1 row
  Non-spillable batteries pass vibration and pressure tests; they are outside ADR if no electrolyte flows at 55 °C and terminals are protected.
• 239 · 1 row
  Sodium batteries/cells: only sodium, sulphur or sodium compounds; no liquid sodium at offer unless authority-approved; sealed metal casings required.
• 241 · 1 row
  Formulation must stay homogeneous; low-nitrocellulose formulations passing test series 1 (a), 2 (b), 2 (c) and test N.1 are outside ADR.
• 242 · 1 row
  Sulphur formed to a specific shape (prills, granules, pellets, pastilles or flakes) is not subject to ADR.
• 243 · 1 row
  Gasoline, motor spirit and petrol for spark-ignition engines go under this entry whatever their volatility.
• 247 · 1 row
  Beverages over 24 % and up to 70 % alcohol in manufacture may go in wooden barrels over 250 up to 500 litres, under four conditions.
• 249 · 1 row
  Ferrocerium stabilized against corrosion with at least 10 % iron is not subject to ADR.
• 250 · 1 row
  Only for chemical samples taken for Chemical Weapons Convention analysis; prior approval, ICAO PI 623 packing and approval copy required.
• 251 · 1 row
  Chemical and first aid kits: only EQ or LQ-qualifying goods, max 1 l or 1 kg per kit; kits on board for vehicle use are outside ADR.
• 252 · 1 row
  Hot concentrated ammonium nitrate solutions: entry use needs ≤ 93 % AN, ≥ 7 % water, max 140 °C etc.; ≤ 80 % solutions meeting (2) are outside ADR.
• 267 · 1 row
  Type C blasting explosives with chlorates must be kept apart from explosives that contain ammonium nitrate or other ammonium salts.
• 271 · 1 row
  Lactose, glucose or similar may serve as phlegmatizer at 90 % or more by mass; at 98 % or more the mixture leaves ADR entirely.
• 273 · 1 row
  Self-heating-stabilized maneb need not go in Class 4.2 if a 1 m³ test sample held at 75 °C for 24 h neither self-ignites nor exceeds 200 °C inside.
• 278 · 1 row
  Not to be classified or carried without competent authority approval based on Series 2 and Series 6(c) tests; the authority sets the packing group.
• 280 · 1 row
  Covers vehicle, vessel and aircraft safety devices (air bags, seat-belt pretensioners) that passed test series 6(c) without dangerous effects.
• 283 · 1 row
  Gas-filled shock absorbers and pneumatic springs are outside ADR if gas space ≤ 1.6 L, charge ≤ 280 bar, litres × bar ≤ 80 and conditions (a)-(e) are met.
• 284 · 1 row
  Chemical oxygen generators with oxidizers: excluded from Class 1 if explosive-actuated, must survive a 1.8 m drop, and need two safeguards against actuation.
• 286 · 1 row
  Nitrocellulose membrane filters of 0.5 g or less each are outside ADR when each is inside an article or a sealed packet.
• 288 · 1 row
  No classification or carriage without competent authority approval resting on Series 2 and Series 6(c) test results.
• 291 · 1 row
  Flammable liquefied gas must be inside refrigerating machine parts tested to 3 × working pressure; machines with under 12 kg of gas are outside ADR.
• 301 · 1 row
  For machinery or apparatus holding dangerous goods as residue or integral part, limited to LQ-eligible goods within column (7a) per item.
• 302 · 1 row
  Fumigated cargo transport units with no other dangerous goods are subject only to 5.5.2.
• 304 · 1 row
  Only for non-activated batteries with dry potassium hydroxide, activated by adding water to each cell before use.
• 307 · 1 row
  Only for ammonium nitrate based fertilizers, classified by Manual Part III Section 39 within the limits of 2.2.51.2.2.
• 316 · 1 row
  Applies only to dry calcium hypochlorite carried as non-friable tablets.
• 321 · 1 row
  These storage systems are always treated as containing hydrogen.
• 324 · 1 row
  Must be stabilized at concentrations of 99 % or less.
• 332 · 1 row
  Magnesium nitrate hexahydrate is not subject to ADR.
• 333 · 1 row
  Ethanol-petrol mixtures for spark-ignition engines go under this entry whatever their volatility.
• 338 · 1 row
  Liquefied flammable gas fuel cell cartridges: withstand 2 × equilibrium pressure at 55 °C, at most 200 ml gas, vapour pressure ≤ 1 000 kPa, hot water bath test.
• 339 · 1 row
  Metal hydride hydrogen fuel cell cartridges: ≤ 120 ml water capacity, ≤ 5 MPa at 55 °C, plus drop, fire, cycling and leak tests and marking.
• 345 · 1 row
  Gas in open cryogenic glass vacuum-insulated receptacles of 1 litre or less is outside ADR when each is cushioned in an outer packaging.
• 346 · 1 row
  P203-compliant open cryogenic receptacles holding only UN 1977 nitrogen fully absorbed in porous material face no other ADR rules.
• 349 · 1 row
  Mixtures of a hypochlorite with an ammonium salt are prohibited; UN 1791 hypochlorite solution is Class 8.
• 352 · 1 row
  Ammonium chlorite, its water solutions, and chlorite-ammonium salt mixtures are prohibited from carriage.
• 355 · 1 row
  Emergency oxygen cylinders may include 1.4C or 1.4S actuating cartridges, up to 3.2 g propellant each, and remain Class 2.
• 356 · 1 row
  Metal hydride storage systems for installation in vehicles, vessels, aircraft or machinery need prior approval by the country of manufacture.
• 358 · 1 row
  Nitroglycerin in alcohol at over 1 % up to 5 % may be Class 3, UN 3064, if every requirement of P300 is met.
• 359 · 1 row
  Nitroglycerin in alcohol at over 1 % up to 5 % is Class 1, UN 0144, unless every requirement of P300 is met.
• 361 · 1 row
  Electric double layer capacitors above 0.3 Wh: protection and marking rules, with exemptions for non-DG electrolytes, ≤ 10 Wh units and packed equipment.
• 369 · 1 row
  Excepted-package radioactive material that is toxic and corrosive is Class 6.1 with radioactive and corrosive subsidiary hazards; no Class 7 label.
• 370 · 1 row
  Only for ammonium nitrate with over 0.2 % combustibles, or at most 0.2 % but positive in test series 2; not for grades with their own name.
• 371 · 1 row
  Articles with a small pressure receptacle and release device: ≤ 0.5 L, ≤ 25 bar at 15 °C, 4 × burst margin, fire and initiation tests, maker records.
• 372 · 1 row
  Asymmetric capacitors above 0.3 Wh: protection and marking rules, with exemptions for non-DG electrolytes, ≤ 20 Wh units and packed equipment.
• 373 · 1 row
  Neutron radiation detectors with boron trifluoride: per-detector limits, packing rules and a document statement; ≤ 1 g units are outside ADR.
• 382 · 1 row
  Expandable polymeric beads need not use this UN number if test U1 shows no flammable vapour forms; test only when de-classifying.
• 383 · 1 row
  Celluloid table tennis balls are not subject to ADR when each weighs no more than 3.0 g and a package holds no more than 500 g net.
• 389 · 1 row
  Lithium batteries fitted in a cargo transport unit only to power external loads: 2.2.9.1.7.1 compliance, secure fixing, and orange plates plus placards.
• 395 · 1 row
  Entry restricted to Category A solid medical waste carried for disposal.
• 396 · 1 row
  Large robust articles may travel with connected nitrogen or air cylinders with valves open, notwithstanding 4.1.6.5, under listed conditions.
• 397 · 1 row
  Nitrogen-oxygen mixtures with 19.5 % to 23.5 % oxygen by volume may use this entry if no other oxidizing gas is present; no 5.1 subsidiary label needed.
• 398 · 1 row
  Entry covers butylene mixtures, 1-butylene, cis-2-butylene and trans-2-butylene; isobutylene is UN 1055.
• 402 · 1 row
  Substances under this entry need a 70 °C vapour pressure of at most 1.1 MPa (11 bar) and a 50 °C density of at least 0.525 kg/l.
• 403 · 1 row
  Nitrocellulose membrane filters (≤ 53 g/m², ≤ 300 g per inner packaging) are not subject to ADR when interleaved and packed as specified.
• 404 · 1 row
  Vehicles powered by short-circuited sodium ion batteries, with no other dangerous goods, are not subject to further ADR provisions.
• 501 · 1 row
  Molten naphthalene is UN 2304.
• 505 · 1 row
  Magnesium diamide (UN 2004) is Class 4.2.
• 507 · 1 row
  Aluminium phosphide pesticides with additives inhibiting toxic flammable gas emission (UN 3048) are Class 6.1.
• 509 · 1 row
  Chlorite solution (UN 1908) is Class 8.
• 510 · 1 row
  Chromic acid solution (UN 1755) is Class 8.
• 516 · 1 row
  Methyl chloride and methylene chloride mixture (UN 1912) is Class 2.
• 522 · 1 row
  Perchloric acid solution > 50 % to ≤ 72 % (UN 1873) is Class 5.1; above 72 %, or mixed with non-water liquids, carriage is prohibited.
• 526 · 1 row
  Celluloid (UN 2000) is Class 4.1.
• 528 · 1 row
  Fibres or fabrics impregnated with weakly nitrated, non-self-heating cellulose (UN 1353) are Class 4.1.
• 533 · 1 row
  Flammable formaldehyde solutions (UN 1198) are Class 3; non-flammable solutions under 25 % formaldehyde are not subject to ADR.
• 534 · 1 row
  Petrol with a 50 °C vapour pressure up to 150 kPa (1.50 bar) in some climates is still treated as not exceeding 110 kPa (1.10 bar).
• 535 · 1 row
  Lead nitrate (UN 1469) and lead perchlorate solid (UN 1470) and solution (UN 3408) are Class 5.1.
• 536 · 1 row
  Solid naphthalene is UN 1334.
• 537 · 1 row
  Non-pyrophoric titanium trichloride mixture (UN 2869) is Class 8.
• 538 · 1 row
  Solid sulphur is UN 1350.
• 539 · 1 row
  Isocyanate solutions with a flash-point of 23 °C or higher are Class 6.1.
• 542 · 1 row
  Talc containing tremolite and/or actinolite falls under this entry.
• 545 · 1 row
  Dipicryl sulphide (UN 0401) wetted with under 10 % water by mass is Class 1.
• 546 · 1 row
  Dry finished zirconium sheet, strip or coiled wire under 18 µm thick (UN 2009) is Class 4.2; 254 µm or thicker is not subject to ADR.
• 547 · 1 row
  Maneb and maneb preparations in self-heating form (UN 2210) are Class 4.2.
• 549 · 1 row
  Chlorosilanes not emitting flammable gas with water: Class 3 if flash-point below 23 °C, Class 8 if 23 °C or above.
• 550 · 1 row
  Cerium in slabs, rods or ingots (UN 1333) is Class 4.1.
• 553 · 1 row
  This hydrogen peroxide/peroxyacetic acid mixture must show no explosive behaviour and SADT ≥ 60 °C (50 kg); otherwise it is Class 5.2.
• 566 · 1 row
  Hydrazine aqueous solution (UN 2030) with more than 37 % hydrazine by mass is Class 8.
• 568 · 1 row
  Barium azide wetted below the stated water content is an explosive, Class 1, UN 0224.
• 581 · 1 row
  Covers propadiene with 1–4 % methylacetylene and the named mixtures P1 and P2, which may be described as "Mixture P1"/"Mixture P2".
• 582 · 1 row
  Covers refrigerant gas mixtures F1, F2 and F3, defined by maximum vapour pressure at 70 °C and minimum density at 50 °C.
• 590 · 1 row
  Ferric chloride hexahydrate is not subject to ADR.
• 591 · 1 row
  Lead sulphate with at most 3 % free acid is not subject to the Class 8 requirements.
• 597 · 1 row
  Acetic acid solutions with at most 10 % pure acid by mass are not subject to ADR.
• 600 · 1 row
  Fused and solidified vanadium pentoxide is not subject to ADR.
• 607 · 1 row
  Potassium nitrate plus sodium nitrite mixed with any ammonium salt: carriage prohibited.
• 609 · 1 row
  Tetranitromethane containing combustible impurities is prohibited from carriage.
• 610 · 1 row
  Carriage is prohibited when the substance contains more than 45 % hydrogen cyanide.
• 611 · 1 row
  Ammonium nitrate with over 0.2 % combustible substances is prohibited unless part of a Class 1 substance or article.
• 613 · 1 row
  Chloric acid solution above 10 % chloric acid, or chloric acid mixed with any non-water liquid, is prohibited.
• 616 · 1 row
  Substances with more than 40 % liquid nitric esters must pass the 2.3.1 exudation test.
• 618 · 1 row
  Receptacles of 1,2-butadiene: oxygen in the gas phase must not exceed 50 ml/m³.
• 623 · 1 row
  Sulphur trioxide (UN 1829) must be inhibited, except ≥ 99.95 % pure in tanks kept at ≥ 32.5 °C, with a document statement.
• 639 · 1 row
  Cross-reference to 2.2.2.3, classification code 2F, UN 1965, note 2.
• 640I · 1 row
  SP 640 letter I: "Special provision 640I" in the document for ADR tanks; marks UN 1790 hydrofluoric acid with more than 85 % hydrogen fluoride.
• 640J · 1 row
  SP 640 letter J: "Special provision 640J" in the document for ADR tanks; marks UN 1790 hydrofluoric acid with > 60 % to ≤ 85 % HF.
• 640K · 1 row
  SP 640 letter K: "Special provision 640K" for ADR tanks; marks UN 1202 gas oil/diesel/light heating oil, flash-point ≤ 60 °C.
• 640L · 1 row
  SP 640 letter L: "Special provision 640L" for ADR tanks; marks UN 1202 diesel/gas oil/light heating oil meeting EN 590:2013 + A1:2017.
• 640M · 1 row
  SP 640 letter M: "Special provision 640M" for ADR tanks; marks UN 1202 gas oil/diesel/light heating oil, flash-point > 60 °C to ≤ 100 °C.
• 640N · 1 row
  SP 640 letter N: "Special provision 640N" for ADR tanks; marks UN 2015 hydrogen peroxide, stabilized, above 70 %.
• 640O · 1 row
  SP 640 letter O: "Special provision 640O" for ADR tanks; marks UN 2015 hydrogen peroxide solution, stabilized, > 60 % to ≤ 70 %.
• 642 · 1 row
  Not to be used for fertilizer ammoniating solutions with free ammonia unless authorized under 1.1.4.2; see UN 2073, 2672, 3318.
• 646 · 1 row
  Carbon produced by steam activation is not subject to ADR.
• 647 · 1 row
  Vinegar and food-grade acetic acid ≤ 25 % pure acid are subject only to the listed material, inspection, filling and sealing rules.
• 651 · 1 row
  V2 (1) does not apply when net explosive mass is ≤ 4 000 kg per transport unit and ≤ 3 000 kg per vehicle.
• 654 · 1 row
  Separately collected waste lighters may go for disposal under P003 with water-filled, vented rigid packagings of ≤ 60 l.
• 658 · 1 row
  EN ISO 9994:2019 lighters and lighter refills may go under limited-quantity rules with packages ≤ 10 kg and ≤ 100 kg per vehicle.
• 663 · 1 row
  Only for emptied packagings/IBCs sent to disposal or recycling with adhering Class 9, 8, 6.1, 5.1, 4.1 or 3 residues, with exclusions.
• 671 · 1 row
  For 1.1.3.6, kits take transport category 3, 2 or 1 by packing group III, II or I; kits with no packing group take category 2.
• 672 · 1 row
  Machinery or apparatus under this entry and SP 301 are exempt from other ADR rules if in strong outer packaging or self-protecting.